Gallium(III) Iodide
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Gallium(III) iodide is the
inorganic compound In chemistry, an inorganic compound is typically a chemical compound that lacks carbon–hydrogen bonds, that is, a compound that is not an organic compound. The study of inorganic compounds is a subfield of chemistry known as '' inorganic chemist ...
with the
formula In science, a formula is a concise way of expressing information symbolically, as in a mathematical formula or a ''chemical formula''. The informal use of the term ''formula'' in science refers to the general construct of a relationship betwee ...
Ga I3. A yellow hygroscopic solid, it is the most common iodide of gallium. In the
chemical vapor transport In chemistry, a chemical transport reaction describes a process for purification and crystallization of non- volatile solids. The process is also responsible for certain aspects of mineral growth from the effluent of volcanoes. The technique is ...
method of growing crystals of
gallium arsenide Gallium arsenide (GaAs) is a III-V direct band gap semiconductor with a Zincblende (crystal structure), zinc blende crystal structure. Gallium arsenide is used in the manufacture of devices such as microwave frequency integrated circuits, monoli ...
uses iodine as the transport agent. In the solid state, it exists as the dimer Ga2I6.


"Gallium(I) iodide"

Gallium triiodide can be reduced with gallium metal to give a green-colored solid called "gallium(I) iodide." The nature of this species is unclear, but it is useful for the preparation of compounds of gallium(I) and gallium(II) and is reported as useful in organic syntheses.GaI: A new reagent for chemo- and diastereoselective C–C bond forming reactions, Green SP, Jones C., Stasch A., Rose R.P, New J. Chem., 2007, 31, 127 - 134,


See also

* Gallium halides * "GaI"


References

Iodides Gallium compounds Metal halides {{inorganic-compound-stub